Engineers TV

As a member of Engineers Ireland you have access to Engineers TV, which contains over 700 presentations, technical lectures, courses and seminar recordings as well as events and awards footage and interviews.

Silicate, a terrestrial enhanced weathering company headquartered at NovaUCD in Dublin, today announced that it has been named as one of 20 finalists in the XPRIZE Carbon Removal competition. Silicate is the only company from Ireland among the 20 finalists.

The competition, which is funded by the Musk Foundation, helped catalyse the growth of an entire new industry, galvanising more than 1,300 teams to develop new ideas for carbon dioxide removal (CDR).

The 20 finalists, who are now competing for a $50m grand prize, represent leading CDR solutions with the potential to make meaningful contributions to a diverse, global, sustainable, gigatonne-scale CDR effort.

Durably sequester atmospheric carbon dioxide as dissolved bicarbonate

Silicate’s carbon dioxide removal approach leverages existing agricultural value chains to durably sequester atmospheric carbon dioxide as dissolved bicarbonate by enhancing a natural and permanent carbon removal pathway, weathering. Silicate is the first terrestrial enhanced weathering company globally to focus on carbonate-bearing materials, such as returned concrete and limestone.

Maurice Bryson, founder, Silicate. Photo: Declan Colfer Photography.

Research by the company in Ireland and the US Midwest in collaboration with academics from University College Dublin and Northwestern University, with the support of Breakthrough Energy Fellows, has helped the company to progress on milestones critical to enabling enhanced weathering to become a carbon removal pathway with climate-relevant potential.

“Being selected as a finalist in this prestigious competition is an exciting opportunity for our team to demonstrate the potential of terrestrial enhanced weathering with carbonate-bearing materials to durably sequester atmospheric carbon dioxide,” said Silicate founder and director, Maurice Bryson.

“XPRIZE’s recognition and support of our work is a boon to our mission to leverage agricultural value chains to durably remove excess carbon dioxide from the atmosphere while increasing soil productivity through pH amendment.”

The finalists were selected based upon their performance in three key areas: operations, sustainability, and cost. The finalists demonstrated their ability to execute a substantial demonstration that approaches the competition's goal of removing 1,000 net tonnes of CO2 in the final year of the competition, and a viable pathway to reaching megatonne scale in the coming years and eventually gigatonne scale with an understanding of their environmental and social impacts.

"For the world to effectively address greenhouse gas emissions, carbon removal is an essential element of the path to net zero. There's no way to reverse humanity's impact on the climate without extracting carbon from our atmosphere and oceans," said Anousheh Ansari, chief executive officer, XPRIZE.

Building a set of robust and effective solutions

"We need a range of bold, innovative CDR solutions to manage the vast quantities of CO2 released into our environment and impacting our planet. The teams that have been competing for this prize are all part of building a set of robust and effective solutions and our 20 teams advancing to the final stage of XPRIZE Carbon Removal will have an opportunity to demonstrate their potential to have a significant impact on the climate."

Last year, humans emitted a record 35.8 billion tonnes of carbon dioxide to the atmosphere (Liu et al., 2024). Limiting global warming to 1.5°C – we are currently at ~1.1°C (Lee and Romero, 2023) – will require not just urgent decarbonisation of the global economy, but also permanent removal of 20-660 billion tonnes of carbon dioxide from the atmosphere by 2100 (Shukla et al., 2022).

The 20 finalist teams are in four removal pathway tracks, Air, Rocks, Oceans, Land, Oceans.

Further information on the other finalists visit: https://www.prnewswire.com/news-releases/20-finalists-announced-in-xprize-carbon-removal-racing-to-reverse-climate-change-302138956.html

The final stage of the competition will take place over the next year, wherein finalist teams are challenged to demonstrate 1,000 net tonnes of COremoval and will be judged based on their fully considered cost, operational performance, and against sustainable scalability requirements.

NovaUCD startup Silicate unveiled as finalist in XPRIZE Carbon Removal Competition

There are two distinctive types of electric buses making their way along Nanjing Xi Lu, one of Shanghai's busiest roads.

The first is a fleet of blue trolleybuses that serve bus route number 20, a line set up by a British-run transport company in 1928. They use poles on their roofs to receive electricity from wires overhead and have kept the route running in this way for nearly a century.

But while the historic trolleybuses are a reminder of Europe's past technological innovation, the new buses swooshing alongside them are symbols of China's contemporary net-zero ambition.  

These sleek and modern electric buses, powered by lithium batteries not wires, were rolled out in Shanghai in their thousands beginning in 2014. Compared to the once ubiquitous diesel-fuelled buses, which made loud 'vroom-vroom' engine sounds and belched out black smoke from their tailpipes, the e-buses dominating Shanghai's streets today are quiet, smoke-free and stylish to look at. They also drive smoothly, particularly when they start and stop.

These sleek buses are now ubiquitous across much of China, but their status as a green transport icon was not always assured. As they shuttle back and forth along their bustling daily routes, these vehicles are having a profound influence on not just China's rapid EV transition, but the world's. 

Electric buses have a long history in China, dating back to the 1920s – but China's new generation of electric buses is world-leading in the 21st century. Image: Getty Images. 

An uphill start

The country's decision to spur the manufacturing and use of e-buses was primarily a strategy for industrial growth, then a part of its efforts to curb air pollution. It was only after the government's 2020 pledge to become carbon neutral before 2060 that promoting electric vehicles has become an important part of its climate goals. Yet it appears to be working. 

China now boasts the world's largest market for e-buses, making up more than 95% of global stock

 

The most recent data available shows that China in 2018 was still the second largest source of carbon dioxide (CO2) emissions in the global transport sector, responsible for 11%, and behind only the United States, which accounted for 21%. However, in order to help reduce transport emissions around the world, the International Energy Agency has called for policies to encourage public transport and electric vehicles – and China's e-bus roll out is helping achieve both. 

After about two decades of government support, China now boasts the world's largest market for e-buses, making up more than 95% of global stock. At the end of 2022, China's Ministry of Transport announced that more than three-quarters (77% or 542,600) of all urban buses in the country were "new energy vehicles", a term used by the Chinese government to include pure electric, plug-in hybrids, and fuel cell vehicles powered by alternative fuels such as hydrogen and methanol. In 2022, about 84% of the new energy bus fleet was pure electric. 

The speed of this transition was remarkable. In 2015, 78% of Chinese urban buses still used diesel or gas, according to the World Resources Institute (WRI). The NGO now estimates that if China follows through on its stated decarbonisation policies, its road transport emissions will peak before 2030.

China is also home to some of the world's biggest electric bus manufacturers, such as Yutong, which has been raking up orders across China, Europe, and Latin America.

"China has really been at the forefront of success in conversion of all vehicles to electric vehicles, especially buses," says Heather Thompson, chief executive officer of the Institute for Transportation and Development Policy (ITDP), a non-profit focusing on sustainable transport solutions. "The rest of the world is trying to do the same, but I think China is really out ahead."

So how did China make this world-leading leap? 

A new track

At the time of China's 2001 entry into the World Trade Organization, the international automotive industry was dominated by European, US and Japanese brands. These companies had spent decades perfecting internal combustion engine technology. To compete, Beijing decided to find a new track for its auto industry: making cars that did not use conventional engines.

That same year, the central government launched the so-called 863 plan for EV research and development. There were numerous practical challenges, however, in the way of mass electrification. Not many manufacturers were making new energy vehicles, buyers were few and there was a lack of charging infrastructure in existence. The answer? Buses. 

The regular nature of the bus route lent itself to electrification, with the opportunity to charge vehicles overnight in a planned spot. Image: Getty Images. 

"The Chinese government adopted a very smart strategy," says Liu Daizong, ITDP's East Asia director. "They realised quite early on that they should drive [the EV industry] through electric buses," he notes, since their public service status meant Beijing "could have a strong hand on their electrification".

There were also technological reasons to make buses the spearhead of an electric vehicle revolution. "Bus routes were fixed. This means when an electric bus finished a round, it could return to the depot to recharge," explains Xue Lulu, a mobility manager at the World Resources Institute (WRI) China. The typical daily mileage of a Chinese bus ­– 200km – was a realistic range for battery makers to meet.

Extending the line

China first showed its global EV ambitions at the 2008 Olympics in Beijing. Athletes, guests and spectators were transported around the stadiums by the Ministry of Technology's fleet of 595 'green' vehicles.

The following year, the country began its large-scale rollout of new energy buses, with the Ten Cities and Thousand Vehicles programme. Over three years, the programme aimed to provide 10 cities with financial subsidies to promote 1,000 public-sector new energy vehicles in each, annually. Its goal was to have 10% new energy vehicles in the country by the end of 2012.

Strong policy support from both central and regional governments "gave manufacturers confidence in setting up production lines and stepping up research efforts", says Liu.

By the end of 2012, the programme had reached 25 cities and 27,432 new energy vehicles had been rolled out, reported China Auto News, a newspaper affiliated with state-owned People's Daily Group.

A technological innovation fund was also established by the central government to spur research and development into energy-saving and new energy automotive industry, according to the publication. By December 2013, the fund had awarded a total of 1.6bn yuan (€210m) to 25 projects from 24 companies. 

Together, these strong and consistent government signals encouraged Chinese manufacturers to expand their EV production capacity, bring down costs and improve their technologies. One such company was Build Your Dream, better known as BYD. The Shenzhen-based firm, the world's largest EV maker in 2022, ballooned its business a decade before by supplying electric buses and taxis for China's EV pilot cities.

Making it personal

Progress wasn't straightforward. The Ten Cities, A Thousand Vehicles programme even missed its original three-year, 30,000-vehicle target, with not enough cities showing interest. But a second factor also began pushing cities to embrace new energy buses: air pollution.

"Back then, most buses used diesel, which was a main source of nitrogen oxides (NOx) emissions," says Xue, referring to the air pollution that smothered Beijing and other Chinese cities in the early 2010s. Yet in 2013, a new plan from central government cited tackling air pollution as one of the reasons for rolling out EVs.

This addition proved to be critical: it not only connected EV uptake with people's health, it also indirectly tied the e-bus campaign to local officials' political performance, as the central government would soon hand air-quality targets to all provinces.

In Lvliang, a small city in the coal heartland of Shanxi Province, fleets of e-buses started to appear on the streets about this time, according to Wang Xiaojun, who grew up in the city and now lives in the Philippines, where he runs an NGO called People of Asia for Climate Solutions.

"In the '80s and '90s, there were no buses in Lvliang, only vehicles transporting coal. Most people walked everywhere," he says. As Lvliang started to grow, the local government set up bus routes that used oil-fuelled fleets, but by 2013, many of these had been replaced by electric ones, "most likely because of the pressure [the local government] faced over air pollution". 

The years 2013 and 2014 proved to be important for China's EV push. For the first time, the central government made EV purchase subsidies available to individual consumers, not just the public sector, opening the floodgate to private ownership. Additionally, it offered discounted electricity tariffs to bus operators to make sure the cost of running electric buses would be "significantly lower than" that of their oil or gas-powered equivalents.

The new economic push, plus local government's determination to battle air pollution, generated great enthusiasm for e-buses. By the end of 2015, the number of EV pilot cities rocketed from 25 to 88. In the same year, the central government set a target of 200,000 new energy buses on the road by 2020 and announced a plan to phase out its subsidies for fossil-fuel-powered buses. 

Intense air pollution across many Chinese cities added momentum to the switch to electric vehicles. Image: Getty Images. 

To further stimulate the market, many cities devised various local policies on top of national incentives. For example, Shenzhen, a southern city with a population of more than 17 million, encouraged government agencies to work with private companies to create a full range of renting mechanisms for bus operators.

The battery accounts for 40-50% of an e-bus's total cost, so such rental programmes were key, says ITDP's Liu. Under this method, a bus operator could rent a battery from a manufacturer through a third-party financial organisation, then pay the rent from the money it saved from not having to use more expensive diesel or gas.

Different cities' bus operators also designed different charging strategies. "Buses in Shenzhen had bigger batteries, so they normally charged overnight," says Xue, of WRI China. Between 2016 and 2020, Shanghai, another electric bus hub, subsidised the electricity e-buses used – regardless of the hours of the day – to give them more flexibility in charging.

Generous financial support did lead to problems. In 2016, an EV subsidy fraud shook China, with some bus operators found to have exaggerated the number of e-buses they had purchased. So that same year Beijing shifted its EV subsidy rules so bus operators could only receive financial support when a bus's mileage reached 30,000km.

And finally, one year later, the government announced the so-called dual-credit policy. This allowed new energy vehicle makers to rake up credits which they could sell for cash to those needing to offset 'negative credits' generated from making conventional cars.

As a result of these policies, by 2017 Shenzhen had become the first city globally to replace all of its buses to battery-powered vehicles – with a 2021 study showing that the move had "significantly reduced" greenhouse gas emissions and air pollution in the city. 

Congestion ahead

Growth of China's electric buses now seemed unstoppable. The market was expanding so quickly that in 2018 the government updated its 2020 target for new energy buses from 200,000 to 400,000 and decided it was time to gradually phase out their subsidies. 

There is one charging pillar for every 2.5 of China's 13.1 million new energy vehicles 

 

And it wasn't only China's buses that had benefitted.China's e-bus campaign helped create a big and stable market for its wider EV industry, brought down the costs and created economies of scale. In 2009, the year the e-bus campaign was rolled out, the total number of new energy vehicles sold stood at 2,300; by 2022, it was 6.9 millionanalysis by Huang Zheng, a researcher at the Institute for Internet Industry at Tsinghua University, suggests.

By 2022, the country had also built the world's largest EV charging network, with 1.8 million public charging stations – or two-thirds of the global total – and 3.4 million private equivalents. This means that on average, there is one charging pillar for every 2.5 of China's 13.1 million new energy vehicles.

So far, however, the Chinese cities with the most successful e-bus rollouts – such as Shenzhen, Beijing and Shanghai – all have moderate weather and are relatively flat. To take its e-bus campaign to the next level, China faces challenges.

For one thing, it is difficult to bring fleets to cities such as Hong Kong, which – like London – have double-deckers. These two-storeyed vehicles are "very hard" to electrify, as Xue puts it, because they are heavier, use more energy, and so need bigger batteries, reducing the number of passengers they can carry. One of the few electric double-deck models is produced jointly by BYD and ADL, a UK bus manufacturer.

Cold weather is a problem, too, as it can make a battery's charging time longer and its range shorter. The reason China has not achieved 100% electrification for its buses is its northern regions, which have harsh winters, says Xue.

A further challenge is that the current e-bus manufacturing process can be polluting and emissions-intensive, says Wang; from the mining of raw materials for batteries, such as nickel and lithium, to the production of the steel. The latter is one of the hardest sectors to decarbonise due to the use of coking coal, which not only provides high heat but also acts as an ingredient to enable chemical reactions.

To make e-buses truly 'green', they should also be charged with renewable power, says Wang. But last year coal power still accounted for 58.4% of China's energy mix, according to the China Electricity Council, a trade body. 

The global picture

Globally, however, China is now in a league of its own in uptake of e-buses. By 2018, about 421,000 of the world's 425,000 electric buses were located in China; Europe had about 2,250 and the US owned about 300. According to Alicia García Herrero, a senior fellow at Bruegel, a Brussel-based think tank, Europe has generally been "lagging" in providing "bulky" fiscal support for e-buses.

But earlier this year, the European Commission announced a zero-emission target for all new city buses by 2030. And some countries are increasing their overall funding for the transition.

In 2020, the European Commission approved Germany's plan to double its aid for e-buses to €650m, then again in 2021 to €1.25bn. And the UK, which last year had the largest electric bus fleet in Europe with 2,226 pure electric and hybrid buses, has announced another €153m to help bus operators buy zero-emissions fleets.

While it may be theoretically easy for other countries to kick-start their e-bus rollouts with government subsidies, as China did, a fast deployment also relies on manufacturing capacity and infrastructure, says Ran Ze, a director at the China Representative Office of Environmental Defense Fund, an international environmental advocacy non-profit. "This is something other countries, especially developing nations, will find it hard to copy."

Countries have thus responded to China's manufacturing lead in divergent ways. "While the US has opted for a more competitive angle by fostering its own e-bus production, regions like Latin America are more open to trade with China due to a more friendly trading setup through [China's] Belt and Road initiative," explains Liu.

In order to avoid direct competition from Chinese manufacturers, the US has come up with a "school-bus strategy", says Liu. The Chinese don't make the iconic yellow vehicles, so this could ignite American e-bus manufacturing and create a local industry chain, he suggests. Backed by the US Environmental Protection Agency's $5bn Clean School Bus Programme, the national effort has so far committed to providing 5,982 buses.

In contrast, many Latin American cities, such as the Colombian capital of Bogota and the Chilean capital of Santiago, are greening their traditional bus sectors with the help of Chinese manufacturers, who are the largest providers to the region.

In 2020, Chile became the country that had the most Chinese e-buses outside of China, and this year Santiago's public transport operator announced it has ordered 1,022 e-buses from Beijing-based Foton Motor, the biggest overseas deal the firm had received.

Chinese manufacturers are likely to receive a lot more orders from Chile and its neighbours in this decade. According to latest research by the global C40 Cities network, the number of electric buses in 32 Latin American cities is expected to increase by more than seven times by 2030, representing an investment opportunity of more than €10.5bn.

Thompson, of ITDP, says that a lot of successful Latin American cities have also taken a leaf out of the Chinese book on financing, with electricity companies contributing to the cost, "knowing that ultimately the buses are going to plug into their electricity grid", she says. 

China's remarkably rapid introduction of electric buses has put it front and centre of the global EV market. Image: Getty Images. 

In Europe, however, Chinese e-bus makers are likely to face increasing headwinds. EU policymakers have responded to China's dominance in EV manufacturing with an anti-subsidy investigation, after European Commission President Ursula von der Leyen said that the "global market is flooded with cheaper electric vehicles".

"Amid the global tide to build more resilient supply chains, many are trying to reduce their dependency on China," says García Herrero.

The fast lane to net zero

In June 2023, BloombergNEF forecast half of the world's buses to be entirely battery-powered by 2032, a decade ahead of cars. And by 2026, 36% and 24% of municipal bus sales in Europe and the US, respectively, are expected to be EVs as they begin to catch up with China, BloombergNEF said in a report. But in Thompson's view, the world still has a long way to go electrifying buses, especially in Latin America, Asia and Africa.

"In places like Africa, there are many buses on the streets, but they are not part of the formal public transportation system," she notes. "They are small minibuses that, maybe, were first being used in markets in Europe or Japan, and then exported to Africa."

To meet the global climate goals set by the Paris Agreement, simply switching the world's existing bus fleets might not be enough. According to ITDP, the cumulative greenhouse gas emissions from urban passenger transport globally must stay below the equivalent of 66 gigatonnes CO2 between 2020 and 2050 for the world to meet the 1.5C temperature goal. This emissions limit will only be possible when the world not only adopts electric buses, but goes through a broader shift away from private transport.

"We can't just focus on [replacing] the buses that exist, we need to actually get many, many more buses on the streets," says Thompson. She and her team estimate that the world would need about 10 million more buses through 2030, and 46 million more buses cumulatively through 2050, to make public transport good enough to have a shot at achieving the Paris Agreement. And all those buses will need to be electric.

In China therefore, even though EVs are being sold faster than ever, its central government has instructed cities to encourage public transport use, as well as walking and riding bikes.

Outside residential blocks in the megacity Shanghai, colourful posters showing an e-bus, a bike and a subway train remind passers-by to commute in a low-carbon manner. The main bus operator of another city, Heze, home to nearly nine million people, has also reportedly offered to customise bus routes to suit citizens' needs, such as bypassing schools.

In Wang's home town, meanwhile, which has a little more than three million residents, the local government has gone one step further and made all bus rides free. All citizens need to do is to swipe an app, with no charge, to get onto the bus. "My aunt loves taking buses now," says Wang. "She says it is so convenient."

Wang now believes that even though the manufacturing e-buses can be polluting, making them more accessible is the right way forward – for China and the world.

"Only then can [the government] take the next step – to make the buses' electricity sources, batteries and steel greener in the future," he says. 

Author: This article was written by Xiaoying You and first appeared on the BBC website Future Planet.

How China's buses shaped the world's electric vehicle revolution

With the world facing increasingly dire environmental crises, construction is one of the most significant contributors to global emissions, about 39% of carbon emissions globally, out of which 28% is from energy consumption and 11% from construction materials, also known as embodied carbon. Construction must be transformed to create greener, more sustainable solutions throughout the lifecycle of all assets.

At Diatec group (part of NTI) we work with clients to build digital solutions that form part of the solution to achieve sustainability change. We have a significant track record in implementing these changes with a large cross-section of clients.

What is digital transformation?

Before we look in detail at how digital transformation supports sustainability efforts it is useful to define digital transformation as it is a much-abused term. Digital transformation is simply a catch-all for any activities an organisation undertakes to achieve its business goals utilising digital tools and processes.

It is critical to note that if your digital transformation strategy is not aligned with your business goals, it is nothing more than a vanity project that will waste time and resource. In the context of sustainability, your digital transformation strategy needs to be aligned with your sustainability goals as well.  

Aligning your sustainability goals with digital transformation 

Every organisation we talk to is taking sustainability seriously, we see less green washing in our sector than others. We see contractors using net-zero concrete, recycling materials wherever possible. Lots of us have been using carbon calculators on projects for many years. Architects and engineers are looking to bring sustainability solutions into their designs, their offices are going paperless and working from home common place.

Where we are seeing the most progress and the most successful sustainability programs are organisations that have an overall strategy that is broken down into small, achievable goals, bringing the employees along with them and celebrating the wins – big and small.

The small steps are typically focused on increasing efficiency or reducing environmental impact though better design. While we are seeing some great successes, we do see some failures. To qualify what is meant by failure here is that the activity didn’t deliver the benefits set out at project inception, rather than no benefit delivered at all.

There are several causes of these failures, we have seen the most common being lack of organisational change management strategy, lack of expertise, internal resistance to change, budget constraints, upskilling, and recruitment. As stated earlier digital transformation is the use of digital tools to achieve business goals (very simply).

Similarly digital transformation should be aligned with your sustainability goals. 

As an example of this, ISO19650 the international BIM mandate started life as BS1192 which was the United Kingdom’s BIM standard, which in turn was a result of the ‘Construction 2025 Strategy’ whose main targets were a 50% reduction in construction emissions and a 33% reduction in construction waste.

With a little less than a year to go on this, it will be interesting to see how close they come to hitting the target. Current estimates suggest it has had a positive impact but not nearly close to achieve those ambitious goals. There are numerous other examples around the globe of these attempts at achieving sustainability targets with digital transformation.

Thankfully at a more micro-level success is more prevalent. Individual organisations have implemented changes to analogue working methods, many organisations now work with a digital common data environment, sharing, commenting, and distributing construction data without resorting to paper methods. Sustainability reviews at early design stages create greater scope for significant impact on project outcomes and are happening more and more often. 

Implementing digital transformation with Diatec

All this is a lot to take in, let alone understand what this means for your organisation. The good news is that your business goals, sustainability goals and digital transformation are more than likely very aligned in overall aspirations. Less waste, higher efficiency are common targets for all of the activities. The ‘magic’ is in consciously aligning all three to really achieve remarkable results. 

At Diatec group we work with many organisations in the construction sector, supporting them in getting the right solutions to meet their business goals and drive their digital transformation and sustainability strategies.

We help train staff and implement workflows to achieve these goals and provide the right digital solution for you. We understand the pressures and difficulties the industry faces and believe in an honest and  open dialogue about what practical steps we can take together to reach those goals.

We work hard to understand macro trends in your industry, such as sustainability, digital transformation and can translate these into tangible actions we can take together. 

About the author

Robert Lakey has more than 35 years’ experience working firstly in the construction industry for more than 30 years and more recently in asset management and information technology. He has worked on wide range of construction projects, from roads and bridges, flood defences, factories, ports and harbours. He has also been involved in BIM implementation, software restructuring, and digital transformation for several multi-national consulting businesses. 

To discuss how we can help you or to find out more please feel free to contact Diatec at https://ntidiatec.com/.dw

Digital transformation should be helping you deliver on your sustainability goals

Researchers at the Huazhong University of Science and Technology (HUST) in Wuhan, China, have found a reliable way to fix carbon dioxide gas from the atmosphere into useful chemical products, which scientists call a 'milestone' achievement, the South China Morning Post reported.

As the world looks to clean up the planet's warming carbon dioxide gas from the atmosphere, multiple approaches are being tested in laboratories where the gas can be converted into useful products such as methanol, ethanol, alkanes, or olefins. However, the approach to such conversion systems has a big drawback. They can only work for a hundred hours, making them unsuitable for large-scale operations. 

Why can conversion systems only run for a short time?

Scientists use electrochemical methods in these conversion systems, where an electric charge is applied to change a chemical's properties. For instance, the process involves breaking the chemical bonds between carbon dioxide molecules and adding elements like hydrogen to the mix to produce hydrocarbons such as ethanols or formic acid.

The process is carried out in the presence of an electrolyte where researchers have conventionally an alkaline feedstock. However, the process produces unwanted byproducts, such as carbonates, that attach themselves to the equipment, reducing efficiency. This has limited the lab equipment's lifetime to a few hundred hours.

The researchers at HUST teamed up with those from the University of Auckland, New Zealand. They spent the last five years looking for a viable solution to this problem. Their efforts yielded results when they found an electrolyte that could run the systems for at least 5,000 hours, longer than any known approach so far, marking a significant milestone. When calculated, efficiency of the system was recorded at 93%. 

Putting lead-acid batteries to use

Interestingly, the electrolytes used by the researchers came from spent lead acid batteries that were already looking for a safe method for their disposal. Used extensively in the automotive, energy, and military sectors, lead-acid batteries are a mature technology but have failed to work out simple processes for their disposal. 

Spent lead-acid batteries must be incinerated first before lead ions can be extracted. While lead is a toxic heavy metal, it is also very efficient in converting carbon dioxide. The researchers were looking to use the acidic environments of the batteries to carry out their electrochemical processes. Still, they found that the process was unstable in the environment and corroded the catalysts used.

The researchers then developed a suitable catalyst that was less corrosion-resistant and could accelerate the chemical reactions. The development of such a system allows spent lead acid batteries to be used more productively.

In their demonstration, the research team produced formic acid using carbon dioxide. The chemical has multiple applications in the agricultural sector but can also be used in fuel cells in the future. With further research, the team is confident that it will be able to produce products such as ethylene, referred to as the world's most important chemical, as it has applications in the textile, car, and printing industries.

The team also hopes that its technology will help fossil fuel industries decarbonise their operations, the report added. 

 

Technology turns CO2 into chemicals with 93% efficiency as it performs for record 5,000 hours

Scientists at the US Department of Energy's (DOE) Brookhaven National Laboratory and Columbia University have developed a way to convert carbon dioxide (CO2), a potent greenhouse gas, into carbon nanofibres, materials with a wide range of unique properties and many potential long-term uses. Their strategy uses tandem electrochemical and thermochemical reactions run at relatively low temperatures and ambient pressure.

As the scientists describe in the journal Nature Catalysis, this approach could successfully lock carbon away in a useful solid form to offset or even achieve negative carbon emissions.

"You can put the carbon nanofibres into cement to strengthen the cement," says Jingguang Chen, a professor of chemical engineering at Columbia with a joint appointment at Brookhaven Lab who led the research.

"That would lock the carbon away in concrete for at least 50 years, potentially longer. By then, the world should be shifted to primarily renewable energy sources that don't emit carbon."

As a bonus, the process also produces hydrogen gas (H2), a promising alternative fuel that, when used, creates zero emissions. 

Scientists have devised a strategy for converting carbon dioxide (CO2) from the atmosphere into valuable carbon nanofibres. The process uses tandem electrocatalytic (blue ring) and thermocatalytic (orange ring) reactions to convert the CO2 (teal and silver molecules) plus water (purple and teal) into "fixed" carbon nanofibres (silver), producing hydrogen gas (H2, purple) as a beneficial byproduct. The carbon nanofibres could be used to strengthen building materials such as cement and lock away carbon for decades. Image: Zhenhua Xie/Brookhaven National Laboratory and Columbia University; Erwei Huang/Brookhaven National Laboratory.

Capturing or converting carbon

The idea of capturing CO2 or converting it to other materials to combat climate change is not new. But simply storing CO2 gas can lead to leaks. And many CO2 conversions produce carbon-based chemicals or fuels that are used right away, which releases CO2 right back into the atmosphere.

"The novelty of this work is that we are trying to convert CO2 into something that is value-added but in a solid, useful form," says Chen.

Such solid carbon materials – including carbon nanotubes and nanofibres with dimensions measuring billionths of a metre – have many appealing properties, including strength and thermal and electrical conductivity. But it's no simple matter to extract carbon from carbon dioxide and get it to assemble into these fine-scale structures. One direct, heat-driven process requires temperatures in excess of 1,000 degrees Celsius.

"It's very unrealistic for large-scale CO2 mitigation," says Chen. "In contrast, we found a process that can occur at about 400 degrees Celsius, which is a much more practical, industrially achievable temperature." 

The electrocatalytic-thermocatalytic tandem strategy for CNF production circumvents thermodynamic constraints by combining the co-electrolysis of CO2 and water into syngas (CO and H2) with a subsequent thermochemical process under mild conditions (370-450 °C, ambient pressure). This yields a high CNF production rate. The optimal synergy of iron-cobalt (FeCo) alloy and extra metallic Co enhanced the dissociative activation of syngas, promoting carbon-carbon bond formation for CNF production. Image: Zhenhua Xie/Brookhaven National Laboratory and Columbia University.

The tandem two-step

The trick was to break the reaction into stages and to use two different types of catalysts – materials that make it easier for molecules to come together and react.

"If you decouple the reaction into several sub-reaction steps you can consider using different kinds of energy input and catalysts to make each part of the reaction work," says Brookhaven Lab and Columbia research scientist Zhenhua Xie, lead author on the paper.

The scientists started by realising that carbon monoxide (CO) is a much better starting material than CO2 for making carbon nanofibres (CNF). Then they backtracked to find the most efficient way to generate CO from CO2.

Earlier work from their group steered them to use a commercially available electrocatalyst made of palladium supported on carbon. Electrocatalysts drive chemical reactions using an electric current. In the presence of flowing electrons and protons, the catalyst splits both CO2 and water (H2O) into CO and H2.

For the second step, the scientists turned to a heat-activated thermocatalyst made of an iron-cobalt alloy. It operates at temperatures of about 400 degrees Celsius, significantly milder than a direct CO2-to-CNF conversion would require. They also discovered that adding a bit of extra metallic cobalt greatly enhances the formation of the carbon nanofibres.

"By coupling electrocatalysis and thermocatalysis, we are using this tandem process to achieve things that cannot be achieved by either process alone," says Chen. 

High-resolution transmission electron microscopy (TEM) shows the tip of the resulting carbon nanofibre (left) on the iron-cobalt/cerium oxide (FeCo/CeO2) thermocatalyst. Scientists mapped the structure and chemical composition of newly formed carbon nanofibres (right) using scanning transmission electron microscopy (STEM), high-angle annular dark field (HAADF) imaging, and energy-dispersive x-ray spectroscopy (EDS) (scale bar represents eight nanometres). The images show that the nanofibres are made of carbon (C), and reveal that the catalytic metals, iron (Fe) and cobalt (Co), are pushed away from the catalytic surface and accumulate at the tip of the nanofibre. Image: Center for Functional Nanomaterials/Brookhaven National Laboratory.

Catalyst characterisation

To discover the details of how these catalysts operate, the scientists conducted a wide range of experiments. These included computational modelling studies, physical and chemical characterisation studies at Brookhaven Lab's National Synchrotron Light Source II (NSLS-II) – using the Quick X-ray Absorption and Scattering (QAS) and Inner-Shell Spectroscopy (ISS) beamlines – and microscopic imaging at the Electron Microscopy facility at the Lab's Center for Functional Nanomaterials (CFN).

On the modelling front, the scientists used 'density functional theory' (DFT) calculations to analyse the atomic arrangements and other characteristics of the catalysts when interacting with the active chemical environment.

"We are looking at the structures to determine what are the stable phases of the catalyst under reaction conditions," explains study co-author Ping Liu of Brookhaven's Chemistry Division who led these calculations.

"We are looking at active sites and how these sites are bonding with the reaction intermediates. By determining the barriers, or transition states, from one step to another, we learn exactly how the catalyst is functioning during the reaction."

X-ray diffraction and x-ray absorption experiments at NSLS-II tracked how the catalysts change physically and chemically during the reactions. For example, synchrotron X-rays revealed how the presence of electric current transforms metallic palladium in the catalyst into palladium hydride, a metal that is key to producing both H2 and CO in the first reaction stage.

For the second stage: "We wanted to know what's the structure of the iron-cobalt system under reaction conditions and how to optimise the iron-cobalt catalyst," says Xie. The x-ray experiments confirmed that both an alloy of iron and cobalt plus some extra metallic cobalt are present and needed to convert CO to carbon nanofibres.

"The two work together sequentially," says Liu, whose DFT calculations helped explain the process.

"According to our study, the cobalt-iron sites in the alloy help to break the C-O bonds of carbon monoxide. That makes atomic carbon available to serve as the source for building carbon nanofibres. Then the extra cobalt is there to facilitate the formation of the C-C bonds that link up the carbon atoms," she explains.

Recycle-ready, carbon-negative

"Transmission electron microscopy (TEM) analysis conducted at CFN revealed the morphologies, crystal structures, and elemental distributions within the carbon nanofibres both with and without catalysts," says CFN scientist and study co-author Sooyeon Hwang.

The images show that, as the carbon nanofibres grow, the catalyst gets pushed up and away from the surface. That makes it easy to recycle the catalytic metal, says Chen.

"We use acid to leach the metal out without destroying the carbon nanofibre so we can concentrate the metals and recycle them to be used as a catalyst again," he says.

This ease of catalyst recycling, commercial availability of the catalysts, and relatively mild reaction conditions for the second reaction all contribute to a favourable assessment of the energy and other costs associated with the process, say the researchers.

"For practical applications, both are really important – the CO2 footprint analysis and the recyclability of the catalyst," says Chen. "Our technical results and these other analyses show that this tandem strategy opens a door for decarbonising CO2 into valuable solid carbon products while producing renewable H2."

If these processes are driven by renewable energy, the results would be truly carbon-negative, opening new opportunities for CO2 mitigation.

Researchers reveal how catalytic combo converts CO2 to solid carbon nanofibres

The fossil fuel industry lost out on almost €1bn last year – with an additional €300m saved on carbon credits – as wind farms provided 35% of the island’s electricity and set a new record for the amount of power they produced.

The figures come from Wind Energy Ireland’s annual report and a new analysis published by energy specialists Baringa entitled 'Cutting Carbon, Cutting Bills: Analysis of savings in gas consumption delivered by wind farms in 2023'.

The Baringa analysis found that without wind energy, Ireland would have had to spend an additional €918m on gas, most of which would have been imported, for power generation in 2023 and an extra €358m on carbon credits to burn that gas. An additional €279m was saved in Northern Ireland.

Equivalent to the amount of carbon produced by 1.9 million cars

They also estimate that Irish wind farms saved about 4.2 million tonnes of carbon last year which is roughly equivalent to the amount of carbon produced by 1.9 million cars.

The total amount saved on gas of nearly €1.3bn was down on the €2bn saved in 2022 due to significantly lower wholesale gas prices over the past year.

Noel Cunniffe, CEO of Wind Energy Ireland, said: “Electricity generated from Irish wind farms replaces imported fossil fuels. The more wind we can get on the electricity grid, the less we rely on imported gas and the more we can cut our carbon emissions and keep that money at home.

“Our members can be proud of the role Irish wind farms are playing in supporting Irish electricity consumers and reducing our carbon emissions. It is a true success story, and we are on the way to an energy independent future for Ireland. 

“But we cannot build the wind farms we need to achieve energy independence without a planning system that is fit for purpose and we cannot get the power to where it is needed without support for EirGrid and ESB Networks to develop a much stronger electricity grid.

“Progress to date on the Planning and Development Bill has been welcomed by industry and the government’s plan to put in place mandatory timelines for planning decisions as part of the new legislation needs to be fully supported. Both planning reform and grid reinforcement must remain top priorities right across the political system in 2024.”

Wind’s best year on record

Wind Energy Ireland confirmed that wind farms provided 35% of Ireland and Northen Ireland’s electricity in 2023, totalling a record breaking 13,725 gigawatt-hours (GWh).

This figure represents the largest annual amount of wind power generated by our wind farms to date and it is equivalent to the electricity consumption of more than three million Irish families, surpassing the previous record of 13,699 GWh set in 2020.

It follows a particularly strong performance last month with wind energy providing exactly half the country’s electricity, making it the best month for wind power generation in 2023.

There is also more good news for consumers as the average wholesale price of electricity in December 2023 was €88.97 per megawatt-hour (MWh), down 68 per cent from €276.52 in December 2022 raising the possibility of these savings being passed on to consumers in the coming months.

Cunniffe concluded: “We know that consumers and businesses are struggling every day with high energy bills. They need their electricity to be affordable as well as clean.

“The continued annual fall in wholesale electricity prices is welcome news. We are gradually starting to see these price reductions being passed onto consumers in their energy bills and we hope to see this continue in 2024.

“The good news is that if we continue investing in renewables, if government, industry and communities work closely together, we can and will do even more to bring energy bills under control and make Ireland energy independent.”

Record set for wind power generation in 2023: Irish wind farms reduce gas spend by almost €1.3bn

Theme picker