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Scientists at the US Department of Energy's Pacific Northwest National Laboratory (PNNL) have created a system that efficiently captures CO2 before it can reach the atmosphere.

Crucially, it is also the least costly method devised to date, as per a PNNL press statement. The method also converts CO2 into methanol, which is widely used and can be sold after the process is complete. 

Several measures aimed at mitigating the worst effects of climate change

The Intergovernmental Panel on Climate Change (IPCC) offered a dire warning to the world with its climate change report last year. The report outlined several measures aimed at mitigating the worst effects of climate change. The report highlighted the fact that simply reducing emissions was no longer enough; we will also have to remove CO2 from the atmosphere using carbon capture and storage technologies.

Though carbon capture may be a crucial component in the fight against climate change, scientists are working hard to develop methods that are viable from a business perspective. Up to now, the high cost of carbon capture technology has been a barrier to its widespread development on a global scale.

The PNNL scientists believe their new method provides a strong financial incentive in the form of menthol. The chemical is widely used as a fuel and is a key ingredient in plastics, paint, and construction materials. 

 

PNNL chemist David Heldebrant, who led the team behind the new method, compared the new system to recycling. "That's essentially what we're trying to do here. Instead of extracting oil from the ground to make these chemicals, we're trying to do it from CO2 captured from the atmosphere or from coal plants, so it can be reconstituted into useful things.

"You're keeping carbon alive, so to speak, so it's not just 'pull it out of the ground, use it once, and throw it away.' We're trying to recycle the CO2, much like we try to recycle other things like glass, aluminium, and plastics." 

A new world of 'CO2 conversion chemistry'

Heldebrant and his team, who published a paper detailing their method in the journal Advanced Energy Materials, designed their system to fit inside coal, gas, and biomass-fired power plants, as well as cement kilns and steel plants.

In their tests, they used a capture solvent developed at PNNL to catch CO2 molecules before they're emitted. The solvent then converts them into methanol and other substances.

Though Heldebrant and his team do concede that the new method still requires a long research and development phase before going to market, the method could also help to store CO2 in materials that are not burnt back into the atmosphere.

As such, as Casie Davidson, manager for PNNL's carbon management and fossil energy market sector, said: "The team's integrated approach opens up a world of new CO2 conversion chemistry. There's a sense that we're standing on the threshold of an entirely new field of scalable, cost-effective carbon tech. It's a very exciting time."

One method developed by RMIT University researchers in Australia quickly converts CO2 into solid carbon, while another developed by UCLA researchers mimics the seashell-forming process. While these methods may be effective, they arguably don't provide as strong a financial incentive as the new PNNL method. And that could be key to turning the tide on climate change. 

 

Revealed: The least costly carbon capture method to date

Ireland’s greenhouse gas emissions increased by 4.7% in 2021 compared to 2020 and are now 1.1% above 2019 pre-Covid restriction levels, the EPA has revealed. 

  • Emissions from the energy industries sector increased by 17.6% in 2021, driven by a tripling of coal and oil use in electricity generation. 
  • Agriculture emissions increased by 3% in 2021, driven by increased fertiliser use (up 5.2%) and a 2.8% increase in the number of dairy cows.
  • Residential greenhouse gas emissions decreased by 4.9% in 2021, driven by a combination of less time in the home, a milder winter and increased fuel prices.
  • Transport emissions increased by 6.1% as Covid-19 restrictions lifted, however emissions were 10.5% below the pre-Covid 2019 level.
  • The Provisional 2021 greenhouse gas emission numbers indicate that 23.5% of the carbon budget for the five-year period 2021-2025 has already been used, requiring an 8.4% average annual emissions reduction from 2022-2025 to stay within budget.

The Environmental Protection Agency (EPA) has published its provisional greenhouse gas emissions for Ireland for 2021. The figures show an increase in emissions of 4.7% in 2021 compared to 2020 – when Covid restrictions had led to a significant lowering of emissions.

In total in 2021, 61.53 million tonnes of carbon dioxide equivalent (Mt CO2eq) were emitted, with emissions 1.1% above 2019 pre-Covid restriction levels. The increase is mostly due to a significant increase in emissions from the energy industries sector due to a tripling of coal and oil use in electricity generation in 2021, with increases also seen in the agriculture and transport sectors. 

The figures indicate that in 2021, including land use, land use change and forestry (LULUCF), Ireland has used up 69.3 Mt CO2eq (23.5%) of the 295 Mt CO2eq allowed for in the first of Ireland’s recently approved carbon budgets for the period 2021 to 2025. This means that an average annual emissions reduction of 8.4% (more than 5 Mt CO2eq) per year would be required from 2022-2025 to stay within the budget.

The report also shows that Ireland will exceed its 2021 annual limit under the European Union’s Effort Sharing Regulation (EU 2018/842), without the use of flexibilities, by 2.7 Mt CO2eq. 

Laura Burke, EPA director general and Engineers Ireland vice-president said: “A return to coal use in electricity generation, together with continued growth in emissions from the Agriculture sector and a partial rebound in Transport emissions following the easing of COVID restrictions, have combined to deliver an increase on pre-pandemic levels of emissions. 

The data show the scale of change needed within and across all sectors of Ireland’s economy to make sustained progress in reversing this trend and to meet our EU commitments and National greenhouse gas emission reduction targets.”

Sectors: Summary

Energy industries: Sectoral emissions in the Energy Industries sector showed an increase of 17.6% in 2021, attributable to a tripling of both coal and fuel oil use in electricity generation. The consumption of peat has continued to decline, by 67% in 2021, and is currently at an all-time low within the power generation sector.

There was also a reduction in natural gas use by 8.9% as some plants were offline for a time in 2021. Electricity generated from renewables fell from 42% in 2020 to 35%, due to low rainfall and less wind. This resulted in an increase in the emissions intensity of power generation by 11.9% in 2021 to 331 g CO2/kWh compared with 296 g CO2/kWh in 2020.

Agriculture: Agriculture emissions in 2021 were 23.1 Mt CO2eq, an increase of 3% on 2020. Agricultural emissions did not reduce during Covid restrictions and this is the second year in a row that emissions increased. The most significant drivers for the rise in emissions in 2021 were increased use of synthetic nitrogen fertiliser use of 5.2% and higher dairy cow numbers of 2.8% with an increase in milk production of 5.5%. 

This is the 11th consecutive year that dairy cow numbers rose. Milk output per cow also increased (by 2.5%), therefore increased production was driven by a rise in livestock numbers in conjunction with an increase in milk yield per cow. In 2021, total cattle numbers increased by 0.8%.

In 2021, liming on agricultural soils increased by 49.5%, a welcome measure in improving soil fertility, which should lead to a reduction in fertiliser nitrogen use in future years.

Residential: Greenhouse gas emissions in the Residential sector were 7.04 Mt CO2eq in 2021 and decreased by 4.9% or 0.36 Mt CO2eq compared to 2020. However, emissions in 2020 had risen as a result of increased working from home. Emissions are now 2.8% above pre-pandemic levels in this sector.

A combination of warmer weather, rising fuel prices towards the end of the year and an easing of Covid restrictions contributed to substantial reductions in coal, peat and kerosene use for home heating. 

However, since 2014, fuel use per household has increased by 12% with CO2 emissions per household at 3.8 t CO2 in 2021.

Transport: Increases in traffic volumes during 2021 as Covid-restrictions lifted resulted in a 6.1% rise in transport emissions. Emissions had fallen significantly in the transport sector in 2020 as a result of Covid restrictions. Emissions in this sector remain 10.5% below pre-pandemic levels, and it is unclear if they will rebound fully to that level.

Road transport emissions increased from 9.7 Mt CO2eq in 2020 to 10.3 Mt CO2eq in 2021. At the end of 2021, there were a little less than 47,000 battery electric (BEVs) and plug-in hybrid electric (PHEVs) vehicles in Ireland, approximately 24% of the Climate Action Plan target for 2025 of 195,300 and ahead of a linear uptake trajectory towards that target.

Land use, land use change and forestry (LULULCF):  [Comprising of six land use categories (Forest Land, Cropland, Grassland, Wetlands, Settlements, and Other Land) and Harvested Wood Products.] When included in National total emissions (see detail in notes below), this sector accounts for 11.2% of the total emissions in 2021. The sector is a net source of CO2 eq emissions in all years 1990-2021.

The main source of emissions is the drainage of grasslands on organic soils and the exploitation of wetlands for peat extraction. Forest land and Harvested wood products are a carbon sink (CO2 removal) for all years 1990-2021 although the carbon sink associated with Forest land is on a declining trend due to the age profile of existing forests and a declining afforestation trend.

International aviation: In 2021, total international aviation contributed 1.3 Mt CO2 from more than 52,500 return flights from Irish airports, a significant reduction on recent trends, with international aviation emissions averaging over 3.0 Mt CO2eq per year prior to Covid pandemic. Although not part of Ireland’s total greenhouse gas emissions by international agreement, this is a significant reduction in greenhouse gases being emitted into the atmosphere. 

Stephen Treacy, senior manager, EPA said: “The provisional greenhouse gas emission estimates for 2021 are a cause for concern in relation to achieving Ireland’s binding carbon budget targets. Staying within the current budget now requires deep emission cuts of more than 5 Mt CO2 eq per annum over the succeeding four years.”

Full detail on the Greenhouse Gas Emission Inventory 1990 to 2021 is available on the EPA website and the EPA Greenhouse Gas web resource is also available online.  

Tables 

This publication provides early insight into the annual greenhouse gas emissions in advance of final data being submitted to the EU and UN in 2023. To facilitate the use of this data to assess progress towards achieving Ireland’s Climate Act targets, provisional estimates are being published for the first time in July, a full three months ahead of the previous publication schedule.

2021 is the first year over which compliance with targets set in the Effort Sharing Regulation (ESR) will be assessed. This Regulation sets 2030 targets for emissions outside of the Emissions Trading Scheme (known as ESR emissions) and annual binding national limits for the period 2021-2030. Ireland’s target is to reduce ESR emissions by 30% by 2030 compared with 2005 levels, with a number of flexibilities available to assist in achieving this.

An overview of changes in emissions since the previous year is presented in Table 1 and distance to EU targets in Table 2. 

More trend figures, tables and background information available online

Table 1. Provisional greenhouse gas emissions for 2020 and 2021 for Ireland*

Million tonnes, COeq

2020

2021

% Change 2020-2021

% Change 2019-2021

Agriculture

22.431

23.097

3.0

4.3

Transport

10.285

10.912

6.1

-10.5

Energy Industries

8.738

10.272

17.6

8.8

Residential

7.400

7.040

-4.9

2.8

Manufacturing Combustion

4.552

4.593

0.9

-0.7

Industrial Processes

2.107

2.460

16.8

8.5

F-Gases

0.739

0.738

-0.2

-14.7

Commercial Services

0.843

0.817

-3.0

-2.3

Public Services

0.689

0.663

-3.8

1.6

Waste

0.982

0.937

-4.5

-5.5

LULUCF

6.943

7.767

11.9

12.6

National Total excluding LULUCF

58.766

61.528

4.7

1.1

National Total including LULUCF

65.709

69.295

5.5

2.3

* Final figures will be submitted to the EU and UN in March and April 2023 in line with the agreed reporting timetable.

Table 2. Compliance with EU Effort Sharing Regulation Targets 2021-2030

 

2021

2022

2023

2024

2025

2026

2027

2028

2029

2030

Total greenhouse gas emissions without LULUCF

61,528

 

 

 

 

 

 

 

 

 

- Total verified emissions from stationary installations under Directive 2003/87/EC

15,320

 

 

 

 

 

 

 

 

 

- CO2 emissions from domestic aviation

20

 

 

 

 

 

 

 

 

 

Total ESR emissions

46,188

 

 

 

 

 

 

 

 

 

EU ESR Targets

43,479

42,357

41,235

40,113

38,991

37,869

36,747

35,625

34,503

33,381

Gross distance to target

-2,709

 

 

 

 

 

 

 

 

 

+ annualised ETS flexibility†

1,908

1,908

1,908

1,908

1,908

1,908

1,908

1,908

1,908

1,908

+ annualised projected LULUCF flexibility*

0

0

0

0

0

0

0

0

0

0

Net distance to target

-801

 

 

 

 

 

 

 

 

 

* No flexibility projected to be available under the EPA's "With Existing Measures" scenario 

† Set out in Annex II and Annex III of Commission Implementing Decision (EU) 2020/2126 

 

 

Revealed: Ireland’s 2021 greenhouse gas emissions above pre-Covid levels, says EPA

Endgame for fossil fuels in the Irish power system

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