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Engineers - Vital for Survival of the Planet

Lithium is the non-renewable mineral that makes renewable energy possible – will it become the next oil?

The shift to renewables is chugging along at a record-breaking pace. In 2018, they made up 26.2% of total energy production, and that's expected to rise dramatically over the next several decades.

At the core of the renewable fuel and climate discussion is an equally important discussion about the future of sustainable transportation.

Internal combustion engine or ICE cars may have reached their peak of efficiency, and even when efficient, they still let out harmful gasses into the environment.

Leading the charge for alternative means to power cars are electric vehicles, powered by batteries. Batteries have become central to our daily lives, not just in our cars, but also in our laptops, our phones, practically everything at this point.

All these batteries require something that isn't exactly commonplace or easily sourced though: lithium.

Lithium-ion batteries, or even just lithium-based batteries in general, are drastically more efficient and sustainable than any other battery technique when you factor in cost to the calculation.

They also have significant energy density compared to cost-effective alternatives, which makes them perfect for all our devices, and for our electric cars.

But sourcing the massive amount of lithium needed to keep up all this battery production is actually quite environmentally damaging. In fact, if the infrastructure of sourcing and mining these minerals goes unchecked, it will be verging on an environmental disaster.

How and where lithium is mined


More than 50% of the entire world's lithium reserves are found in the 'lithium triangle' in South America. This area covers Argentina, Bolivia and Chile and it's one of the driest places on earth – which is an issue.

In order to extract lithium minerals from the ground, miners will start by drilling a hole in the ground and pumping in brine into the hole and then leave the brine to rest on the surface.

As the brine rests, the liquid evaporates leaving behind a dense collection of minerals. It takes roughly 12-18 months for everything to evaporate off before the minerals can be collected in a certain region. As you can guess, this takes a ton of water.

The process takes 500,000 gallons per metric ton of lithium produced. For perspective, in Chile, lithium mining consumed 65% of the entire region's water.

This mining process also has the ability to leach other toxic materials into the surrounding water sources through groundwater or acid rain.

The process tends to be a little more refined in North America and more developed countries, but even still, researchers noticed changes in wildlife up to 150 miles (240km) away from the mining sources.

All of this signals that electric cars and battery production as a whole isn't the green haven it promises to be, at least at the onset of finding all the lithium.

Lithium mining at the end of the day is still a mining process, which means it disrupts the environment around it and causes environmental harm that can be far-reaching.

Alternatives and the future


Even with all of this said, lithium is a fairly abundant naturally occurring mineral. There's theoretically plenty of supply to last us for many hundreds of years, leaving room for environmental optimisation in the process.

There are also methods of producing lithium through very energy intensive processes involving sea-water.

The demand for lithium and lithium production continues to skyrocket, as does the price per metric ton. In 2014, the price was roughly $6,500. In 2016, it had climbed to $9,000. Today, the price per metric ton is as high as $17,000.

Lithium production and geography also might play a troubling role in the future of the lithium industry. Most of the world's lithium is located underground land owned by non-wealthy countries.

This has lead and may lead to more unethical mining practices, little care for the environment, and intense political brawls to gain control of this potential future wealth.

This geographic locality of the mineral also allows for the potential of an organisation similar to oil's OPEC to gain control of the production and distribution of the mineral.

In many ways, the way we see the lithium industry, now reaching the end of its phase of infancy, is similar to the beginning of the oil boom.

Can we recycle lithium batteries?


Recycling of lithium batteries is also a fairly new and not widely used process. Batteries, in general, are fairly hard to cost-effectively recycle, so in large part it isn't done.

As lithium cathodes degrade as they are used, it's hard to get an accurate chemical picture of what's taking place in that battery for recycling purposes.

This means that in small-scale battery scenarios, like smartphone or other electronic batteries, it just doesn't make sense to recycle the battery for the potential minuscule chemical payoff.

Modern battery manufacturers also keep their battery technology under lock and key due to the competitiveness of the industry.

This ultimately means that no recycling company can have a good idea of how to recycle a given battery without extensive testing on the batteries themselves. Better yet, due to technology's constant innovation cycles.

At the end of the day, the future of lithium battery production seems bright, but the future of the environment as a result of lithium mining seems a little uncertain.

It's all too common for the consumers of technology that use lithium batteries, simply due to who can afford them, to be unaware of the environmental disaster that the creation of these products are causing on other sides of the world, perhaps in areas where there are no media.

With the rapid growth of technology and battery development, lithium seems poised to be the next oil. Curious how the shift from non-renewable energies like fossil fuels has lead us to a potential renewable energy system – that is completely dependent upon non-renewable environmentally harmful resources.

This article was written by Trevor English and is reproduced with kind permission from InterestingEngineering.com. Find the link to the original article here.

Will lithium be the next oil?

Scientists from Trinity College Dublin have taken a giant stride towards solving a riddle that would provide the world with entirely renewable, clean energy from which water would be the only waste product.

Reducing humanity’s carbon dioxide (CO2) emissions is arguably the greatest challenge facing 21st century civilisation – especially given the ever-increasing global population and the heightened energy demands that come with it.

Use renewable electricity to split water


One beacon of hope is the idea that we could use renewable electricity to split water (H2O) to produce energy-rich hydrogen (H2), which could then be stored and used in fuel cells.

This is an especially interesting prospect in a situation where wind and solar energy sources produce electricity to split water, as this would allow us to store energy for use when those renewable sources are not available.

The essential problem, however, is that water is very stable and requires a great deal of energy to break up. A particularly major hurdle to clear is the energy or 'overpotential' associated with the production of oxygen, which is the bottleneck reaction in splitting water to produce H2.

Although certain elements are effective at splitting water, such as Ruthenium or Iridium (two of the so-called noble metals of the periodic table), these are prohibitively expensive for commercialisation.

Other, cheaper options tend to suffer in terms of their efficiency and/or their robustness. In fact, at present, nobody has discovered catalysts that are cost-effective, highly active and robust for significant periods of time.

So, how do you solve such a riddle? Stop before you imagine lab coats, glasses, beakers and funny smells; this work was done entirely through a computer.

Bringing together chemists and theoretical physicists


By bringing together chemists and theoretical physicists, the Trinity team behind the latest breakthrough combined chemistry smarts with very powerful computers to find one of the “holy grails” of catalysis.

The team, led by Professor Max García-Melchor, made a crucial discovery when investigating molecules which produce oxygen: science had been underestimating the activity of some of the more reactive catalysts and, as a result, the dreaded 'overpotential' hurdle now seems easier to clear.

Furthermore, in refining a long-accepted theoretical model used to predict the efficiency of water splitting catalysts, they have made it immeasurably easier for people (or super-computers) to search for the elusive 'green bullet' catalyst.

Lead author, Michael Craig, TCD, is excited to put this insight to use: "We know what we need to optimise now, so it is just a case of finding the right combinations."

The team aims to now use artificial intelligence to put a large number of earth-abundant metals and ligands (which glue them together to generate the catalysts) in a melting pot before assessing which of the near-infinite combinations yield the greatest promise.

Design of ideal catalysts


In combination, what once looked like an empty canvas now looks more like a paint-by-numbers as the team has established fundamental principles for the design of ideal catalysts.

Professor Max García-Melchor said: "Given the increasingly pressing need to find green energy solutions it is no surprise that scientists have, for some time, been hunting for a magical catalyst that would allow us to split water electrochemically in a cost-effective, reliable way.

"However, it is no exaggeration to say that before now such a hunt was akin to looking for a needle in a haystack.We are not over the finishing line yet, but we have significantly reduced the size of the haystack and we are convinced that artificial intelligence will help us hoover up plenty of the remaining hay.

"This research is hugely exciting for a number of reasons and it would be incredible to play a role in making the world a more sustainable place. Additionally, this shows what can happen when researchers from different disciplines come together to apply their expertise to try to solve a problem that affects each and every one of us."

Prof García-Melchor is an Ussher Assistant Professor in Chemistry at Trinity and senior author on the landmark research that has just been published in a leading international journal, 'Nature Communications'.

Collaborating authors include Gabriel Coulter, formerly of Trinity and now studying for a MSc at the University of Cambridge; Eoin Dolan formerly of Trinity and now completing an Erasmus Mundus joint MSc degree in Paris; Dr Joaquín Soriano-Lòpez, MSCA-Edge fellow in Trinity’s School of Chemistry; Eric Mates, PhD candidate in Trinity’s School of Chemistry and Professor Wolfgang Schmitt from Trinity’s School of Chemistry.

The research has been supported by Science Foundation Ireland and the Irish Centre for High-End Computing (ICHEC), where the team is benefiting from 4,500,000 CPU hours at Ireland’s state-of-the-art super-computer facility.

Trinity researchers take giant stride towards entirely renewable energy

The Sustainable Energy Authority of Ireland (SEAI) and the Department of Communications, Climate Action and Environment (DCCAE) are co-hosting the inaugural National Energy Research and Policy conference on November 20 2019.

This conference, which will be held on Wednesday, November 20, from 8.30am-4pm at the Alex hotel, Fenian St, Dublin 2, will be of particular interest to those working in the energy sector, bringing the energy industry, research and policy communities together, and aiming to:

1.) Facilitate discussion on the role of energy research and policy in achieving Ireland’s long-term clean energy goals
2.) Ensure that energy policy development and implementation is informed by the best research and scientific advice possible
3.) Ensure researchers are aware of current and future energy policy priorities

In the recently published all-of-government Climate Action Plan to tackle climate breakdown, a target was included for 70 per cent of electricity to come from renewable sources by 2030.

This particular challenge will be a focal discussion point, with the 2019 conference theme focusing on Transformation of Ireland’s Electricity Sector.

Minister Richard Bruton will open the conference, followed by presentations and panel discussions from a range of energy industry stakeholders, leading energy researchers, as well as policymakers.

Conference panel discussions will address the role of research and innovation in meeting Ireland’s 2030 energy objectives, as well as the key challenges in transformation of Ireland’s electricity sector.

Speakers and panellists


  • Aoife MacEvilly, CRU
  • Colm De Burca, ESB
  • Eamonn Confrey, DCCAE
  • Dr Lucy Corcoran, SEAI
  • Dr Muireann Lynch, ESRI
  • Dr Paul Deane, UCC
  • Sharon Finegan, Deptartment of the Taoiseach

For the full conference agenda and to register for this event, visit: https://www.seai.ie/events/research-conference/

Please note that although this is a free event, we require a €50 refundable deposit to secure your place, the full amount will be refunded within five days of the event. This deposit helps to ensure we have a high attendance on the day.

Inaugural National Energy Research and Policy conference set for Dublin

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